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Does tinplate coating single-sided white paint possess good high-temperature retortability and make it suitable for canned food?

Publish Time: 2025-11-04
Tinplate, as an important material in the food packaging industry, is widely used in the packaging of canned goods, beverages, milk powder, and other products due to its good mechanical strength, sealing properties, and recyclability. Coating its surface with a layer of white paint not only provides an ideal base for printing but also plays a crucial role in protecting the contents from the substrate. Tinplate coating single-sided white paint does possess good high-temperature retortability and is suitable for high-temperature sterilization processes such as those used in canned food.

1. The Severe Challenges of High-Temperature Sterilization Processes to Coatings

In the production of canned food, high-temperature and high-pressure sterilization is usually used to kill microorganisms and extend shelf life. During this process, the coating on the inner wall of the can must withstand continuous high temperature, high humidity, and chemical erosion from the contents. If the coating's heat resistance is insufficient, problems such as blistering, peeling, discoloration, or damage to the cross-linked structure may occur, affecting not only the appearance but also potentially exposing the metal substrate, leading to corrosion, tin leaching, and even contamination of the contents. Therefore, white paint coatings must possess excellent thermal stability, chemical inertness, and adhesion to withstand this demanding working condition.

2. Specialized Resin Systems Provide Superior Boiling Resistance

Modern tinplate single-sided white paints commonly use epoxy phenolic resins or modified epoxy-acrylic composite systems as film-forming materials. Among these, epoxy phenolic resins, due to their highly cross-linked three-dimensional network structure, maintain molecular chain stability at high temperatures, are not easily softened or degraded, and have extremely strong barrier properties against water vapor and ion penetration, making them the preferred choice for traditional boiling-resistant coatings. In recent years, to balance environmental protection and performance, some high-end products have also introduced BPA-free epoxy alternatives or high-crosslink density polyester/amino systems, ensuring resistance to boiling above 121°C while meeting increasingly stringent food safety regulations. These resins, after high-temperature curing, form a dense and tough paint film that maintains its integrity even under repeated thermal shock.

3. Optimized Formulation Enhances Comprehensive Protective Capabilities

In addition to the main resin, the boiling resistance of white paint coatings also depends on the synergistic optimization of pigments, additives, and curing processes. For example, using high-temperature resistant titanium dioxide as the white pigment not only provides high hiding power and whiteness but also enhances the UV reflectivity of the paint film. Adding coupling agents significantly improves the adhesion between the coating and the tinplate substrate, preventing interfacial delamination during cooking. Reasonable control of curing temperature and time ensures full cross-linking of the resin, forming a stable structure with a high glass transition temperature. Furthermore, the coating thickness also needs precise control—too thin and the protection is insufficient, too thick and it becomes brittle. Generally, the single-sided dry film thickness is controlled between 8–15 micrometers, balancing flexibility and barrier properties.

In summary, tinplate coating single-sided white paint, with its specialized resin system, scientific formulation design, and strict process control, indeed possesses excellent high-temperature cooking resistance, making it perfectly suitable for high-temperature sterilization processes such as food canning. It not only effectively isolates the metal substrate from the contents, preventing corrosion and contamination, but also provides a stable base for subsequent fine printing, making it an indispensable technical guarantee for the safety and quality of modern food packaging.
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